Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

One-dimensional ferromagnetic complexes built with Mn(III)3O units.

Jun Tao1, Yuan-Zhu Zhang, Yue-Lin Bai

  • 1Department of Chemistry, Xiamen University, Xiamen 361005, People's Republic of China, and Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, 816-8580 Fukuoka, Japan.

Inorganic Chemistry
|June 20, 2006
PubMed
Summary

Two novel manganese-based chain complexes were synthesized. Magnetic studies revealed ferromagnetic interactions and field-induced metamagnetism in one complex, advancing materials science.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

FUNDC1 interacts with FBXL2 to govern mitochondrial integrity and cardiac function through an IP3R3-dependent manner in obesity.

Science advances·2020
Same author

The time serial distribution and influencing factors of asymptomatic COVID-19 cases in Hong Kong.

One health (Amsterdam, Netherlands)·2020
Same author

Corrigendum to: COVID-19 Epidemic Doubling Time in the United States Before and During Stay-at-Home Restrictions.

The Journal of infectious diseases·2020
Same author

Predictive value of neutrophil-to-lymphocyte ratio on drug eluting stent restenosis in patients with type 2 diabetes mellitus.

Chinese medical journal·2020
Same author

Awareness and use of HIV pre-exposure prophylaxis among people who engage in sex work presenting to a sexually transmitted infection clinic.

International journal of STD & AIDS·2020
Same author

Coronavirus Disease 2019 Epidemic Doubling Time in the United States Before and During Stay-at-Home Restrictions.

The Journal of infectious diseases·2020

Area of Science:

  • Coordination Chemistry
  • Materials Science
  • Magnetism

Background:

  • Manganese-oxygen clusters are of interest for their unique magnetic properties.
  • Developing novel chain complexes with specific magnetic behaviors is a key research area.

Purpose of the Study:

  • To synthesize and characterize two new chain complexes utilizing non-carboxylate Mn(III)3O units.
  • To investigate the magnetic properties, including intrachain interactions and metamagnetism, of these novel complexes.

Main Methods:

  • Synthesis of two manganese(III) chain complexes: [Mn3O(ppz)3(MeOH)3(OAc)]n (1) and [Mn3O(Meppz)3(MeOH)4(OAc)]n (2).
  • Characterization of the synthesized complexes.
  • Magnetic studies to determine magnetic interactions and properties.

Related Experiment Videos

Main Results:

  • Both complexes exhibit similar intrachain ferromagnetic interactions.
  • Complex 1 displays field-induced metamagnetic properties.
  • The non-carboxylate Mn(III)3O units form the basis of these magnetic chain structures.

Conclusions:

  • The successful synthesis of these complexes provides new examples of magnetic chain materials.
  • The observed magnetic behaviors highlight the tunability of magnetic properties in manganese-based coordination polymers.
  • Further research can explore variations in ligands to fine-tune magnetic characteristics.