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Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
Published on: November 29, 2018
Photochemistry via photoelectron spectroscopy: N-substituted phthalimides
1Charles Sturt University, Orange NSW, Australia. inovak@csu.edu.au
Abstract:
The electronic structures of several N-substituted phthalimides have been investigated by UV photoelectron spectroscopy and outer valence Greens function calculations. Some spectra reveal the presence of photofragmentation and photoelimination processes related to the decay of the aminium radical cation. We compared the fragmentation mechanisms in the gas phase and in the solution.
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