Related Experiment Video
Updated: Aug 7, 2026

High Resolution Phonon-assisted Quasi-resonance Fluorescence Spectroscopy
Published on: June 28, 2016
Sensitivity of arrest in mode-coupling glasses to low-q structure
M J Greenall1, Th Voigtmann, P Monthoux
1Scottish Universities Physics Alliance, School of Physics, The University of Edinburgh, Edinburgh EH9 3JZ, UK.
Abstract:
We quantify, within mode coupling theory, how changes in the liquid structure affect that of the glass. Apart from the known sensitivity to the structure factor S(q) at wave vectors around the first sharp diffraction peak q0, we find a strong (and inverted) response to structure at wave vectors below this peak: an increase in S(q0/2) lowers the degree of arrest over a wide q-range. This strong sensitivity to "caged cage" packing effects, on length scales of order 2d, is much weaker in attractive glasses where short-range bonding dominates the steric caging effect.

