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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
4-(4-Chlorophenyl)-3-(4-phenylpent-4-enyloxy)-1,3-thiazole-2(3H)-thione
Jens Hartung1, Michaela Schwarz, Erich F Paulus
1Organische Chemie, Fachbereich Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger-Strasse, D-67663 Kaiserslautern, Germany. hartung@chemie.uni-kl.de
Abstract:
The title compound, C(20)H(18)ClNOS(2), is a thiazole-derived thiohydroxamic acid O-ester. The value of Z' is 3 and the asymmetric unit comprises three molecules of identical helicity along the N-O bond. Two of these show an anti and the third a syn arrangement of substituents attached in positions 3 and 4 to the 1,3-thiazole nucleus.
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