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Diffuse Reflectance Infrared Spectroscopic Identification of Dispersant/Particle Bonding Mechanisms in Functional Inks
Published on: May 8, 2015
Infrared spectrum of nitric acid dihydrate: Influence of particle shape
Robert Wagner1, Ottmar Möhler, Harald Saathoff
1Forschungszentrum Karlsruhe, Institute of Meteorology and Climate Research (IMK-AAF), Karlsruhe, Germany. Robert.Wagner@imk.fzk.de
Abstract:
In situ Fourier transform infrared (FTIR) extinction spectra of airborne alpha-NAD microparticles generated by two different methods were recorded in the large coolable aerosol chamber AIDA of Forschungszentrum Karlsruhe. The extinction spectrum of alpha-NAD crystals obtained by shock freezing of a HNO3/H2O gas mixture could be accurately reproduced using Mie theory with published refractive indices of alpha-NAD as input. In contrast, Mie theory proved to be inadequate to properly reproduce the infrared extinction spectrum of alpha-NAD crystals which were formed via homogeneous nucleation of supercooled HNO3/H2O solution droplets, evaporating slowly on a time scale of several hours at about 195 K. Much better agreement between measured and calculated extinction spectra was obtained by T-matrix calculations assuming oblate particles with aspect ratios greater than five. This indicates that strongly aspherical alpha-NAD crystals are obtained when supercooled nitric acid solution droplets freeze and grow slowly, a process which has been discussed as a potential pathway to the formation of crystalline polar stratospheric cloud (PSC) particles.
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