Control of the optical properties of quantum dots by surface coating with calix[n]arene carboxylic acids

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Compact Quantum Dots for Single-molecule Imaging
17:14

Compact Quantum Dots for Single-molecule Imaging

Published on: October 9, 2012

Takashi Jin1, Fumihiko Fujii, Eiji Yamada

  • 1Research Institute for Electronic Science, Hokkaido University, Sapporo 060-0812, Japan. jin@imd.es.hokudai.ac.jp

Journal of the American Chemical Society
|July 20, 2006
PubMed

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Aryldiazonium Salts to Azo Dyes: Diazo Coupling01:11

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.