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Strong covalent hydration of terephthalaldehyde
Melek S Baymak1, Kellie L Vercoe, Petr Zuman
1Department of Chemistry, Clarkson University, Potsdam, New York 13699-5810, USA.
Abstract:
Spectrophotometric and electroanalytical studies indicate that one of the formyl groups of terephthalaldehyde in aqueous solution is present in about 23% as a geminal diol. Stronger covalent hydration of CHO in terephthalaldehyde than in p-nitrobenzaldehyde is attributed to a strong resonance interaction between the two formyl groups.
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