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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
The reactivity of all-metal aromatic complexes: a theoretical investigation on the methane activation reaction
Xingbang Hu1, Haoran Li, Congmin Wang
1Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China.
Abstract:
The recent finding of all-metal aromaticity enlightens us to explore the reactivity of all-metal aromatic complexes. The methane activation reaction was chosen for this purpose. The whole catalysis process of all-metal aromatics was investigated by theoretical calculation. The results reveal that the reaction barriers with all-metal aromatic complexes are far lower than that without any catalysts. All-metal aromatic complexes are predicted to have potential to be used as catalysts for the first time.
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