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Updated: Aug 7, 2026
10:51
The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Intermolecular interactions of extended aromatic ligands: the synchrotron molecular structures of
Daniel J Gregg1, Christopher M Fitchett, Sylvia M Draper
1School of Chemistry, Trinity College Dublin, Dublin 2, Ireland.
Chemical Communications (Cambridge, England)
|July 21, 2006
Abstract:
An off-set stack and a saddle-like distortion are revealed by the molecular structures of [Ru(bpy)2(N-HSB)].2PF6 and [Ru(bpy)2(N-(1/2)HSB)].2PF6.
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The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
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