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Molecularly organized Langmuir-Blodgett films from a ruthenium biphosphine complex

K Wohnrath1, C J L Constantino, P A Antunes

  • 1Departamento de Química, UEPG, Ponta Grossa/PR, Brazil. kawoh@uepg.br

The Journal of Physical Chemistry. B
|July 26, 2006
PubMed

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Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation reactions,...