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Inclined N2 desorption in a steady-state N2O + CO reaction on Pd(110)
Yunsheng Ma1, Ivan Kobal, Tatsuo Matsushima
1Catalysis Research Center, Hokkaido University, Sapporo 001-0021 Japan.
Abstract:
The angular and velocity distributions of desorbing products were analyzed in the course of a catalyzed N2O + CO reaction on Pd(110). The reaction proceeded steadily above 450 K, and the N2 desorption merely collimated sharply along 45 degrees off the surface normal toward the [001] direction. It is proposed that this peculiar N2 desorption is induced by the decomposition of adsorbed N2O oriented along the [001] direction. On the basis of the observation of similar inclined N2 desorption in both NO + CO and N2O + CO reactions, the N2 formation via the intermediate N2Oa dissociation was confirmed in catalytic NO reduction.
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