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Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by π-π Stacking Interactions
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pH-responsive diblock copolymer micelles at the silica/aqueous solution interface: Adsorption kinetics and

Kenichi Sakai1, Emelyn G Smith, Grant B Webber

  • 1School of Process, Environmental and Materials Engineering, University of Leeds, Leeds LS2 9JT, United Kingdom. k.sakai@leeds.ac.uk

The Journal of Physical Chemistry. B
|July 28, 2006
PubMed
Summary

The adsorption of pH-responsive poly(2-(dimethylamino)ethyl methacrylate)-block-poly(2-(diethylamino)ethyl methacrylate) (PDMA-PDEA) copolymers onto silica depends on concentration and pH. Copolymers form micelles in alkaline solutions but remain dissolved in acidic solutions, affecting their adsorption behavior.

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