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Optimized Procedure for Determining the Adsorption of Phosphonates onto Granular Ferric Hydroxide using a Miniaturized Phosphorus Determination Method
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Bis(iminodiethylenediammonium) di-mu5-hydrogenphosphato-pentamolybdate(VI) tetrahydrate

Feng Geng1, Guo Hua Han, Bi Zhou Lin

  • 1Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou 362021, People's Republic of China.

Acta Crystallographica. Section C, Crystal Structure Communications
|August 8, 2006
PubMed
Abstract

No abstract available in PubMed .

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Polydentate ligands are most widely used in complexometric titrations because they form more stable complexes with the metal ions than mono- or bidentate ligands due to the chelate effect. Examples of polydentate ligands are ethylenediaminetetraacetic acid (EDTA), crown ethers, and cryptands. The most important feature of optimal polydentate ligands is the ability to form 1:1 complexes in a single-step process. Amino carboxylic acid derivatives are frequently used as complexing agents. EDTA is...
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EDTA titrations are usually carried out in highly basic conditions, where the fully deprotonated form of EDTA, Y4−, actively complexes with the free metal ions in the solution. Several metal ions precipitate as hydrous oxide (hydroxides, oxides, or oxyhydroxides) under these conditions, lowering the concentration of free metal ions in the solution. For this reason, auxiliary complexing agents or ligands such as ammonia, tartrate, citrate, or triethanolamine are used in EDTA titrations to...

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