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Dynamic scaling in entangled mean-field gelation polymers

Chinmay Das1, Daniel J Read, Mark A Kelmanson

  • 1Department of Applied Mathematics, University of Leeds, Leeds, LS2 9JT, UK.

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|August 16, 2006
PubMed
Summary

We developed a reaction kinetics model for branched polymer synthesis, matching experimental structural data. Our model reveals rheological properties, with viscosity discrepancies at high molecular weights potentially due to mean-field behavior near gelation.

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