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Frustrated polyelectrolyte bundles and T= 0 Josephson-junction arrays
Gregory M Grason1, Robijn F Bruinsma
1Department of Physics and Astronomy, University of California at Los Angeles, 90024, USA.
We found a connection between polyelectrolyte bundles and Josephson-junction arrays. This reveals a liquid-to-solid charge transition and universal shear response in polyelectrolyte systems.
Area of Science:
- Condensed matter physics
- Polymer physics
- Materials science
Background:
- Polyelectrolyte bundles exhibit complex phase behaviors.
- Frustrated Josephson-junction arrays are quantum systems with unique transitions.
Purpose of the Study:
- To establish a mapping between hexagonal polyelectrolyte bundles and 2D frustrated Josephson-junction arrays.
- To understand the insulator-to-superconductor transition in quantum systems and its classical analog.
Main Methods:
- Developing a one-to-one correspondence between the two model systems.
- Analyzing the role of vector potential in quantum systems and elastic strain in classical systems.
Main Results:
- The T = 0 insulator-to-superconductor transition maps to a continuous liquid-to-solid charge transition.
- Elastic strain in polyelectrolytes corresponds to vector potential in Josephson junctions.
- The transition involves spontaneous breaking of discrete symmetry related to chiral patterning.
Conclusions:
- Polyelectrolyte bundles exhibit a universal response to shear at the liquid-to-solid transition.
- The established mapping provides new insights into both quantum and classical systems.
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