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Updated: Jul 8, 2026

Sub-nanometer Resolution Imaging with Amplitude-modulation Atomic Force Microscopy in Liquid
Published on: December 20, 2016
Unique organic-inorganic interactions leading to a structure-directed microporous aluminophosphate crystallization as
Matthew G O'Brien1, Andrew M Beale, C Richard A Catlow
1Davy-Faraday Research Laboratory, The Royal Institution of Great Britain, London W1S 4BS, UK.
Abstract:
We report on the direct observation of key organic template-framework interactions leading to the formation of specific aluminophosphate structures. In particular, we show how MeAPO-34 formation was governed by an interaction between the divalent framework substituted metal ion and the template conformation, while for AlPO-5 the structure formation was determined by the template conformation alone. Understanding such interactions therefore appears to be important for the rationalization of microporous material formation.
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