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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
Phosphorus-containing hybrid calixphyrins: promising mixed-donor ligands for visible and efficient palladium
Yoshihiro Matano1, Tooru Miyajima, Takashi Nakabuchi
1Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan. matano@scl.kyoto-u.ac.jp
Abstract:
Phosphorus-sulfur-containing hybrid calixphyrins were prepared by the BF3-promoted dehydrative condensation between sigma4-2,5-bis[(pyrrol-2-yl)methyl]phosphole and 2,5-bis[hydroxy(phenyl)methyl]thiophene. X-ray crystallographic analysis of the Pd-P,N2,S-hybrid calixphyrin complex revealed that the Pd center was coordinated by the four heteroatoms to adopt a distorted square planar geometry. The Pd complex, displaying a characteristic reddish purple color in solution, catalyzed the Heck reaction of bromoarenes with n-butyl acrylate with high efficiency at elevated temperatures.
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