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Related Concept Videos

Preparation and Reactions of Sulfides02:26

Preparation and Reactions of Sulfides

Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
Preparation and Reactions of Thiols02:33

Preparation and Reactions of Thiols

Thiols are prepared using the hydrosulfide anion as a nucleophile in a nucleophilic substitution reaction with alkyl halides. For instance, bromobutane reacts with sodium hydrosulfide to give butanethiol.
Sulfate Attack on Concrete01:29

Sulfate Attack on Concrete

Sulfate attack on concrete is a deterioration process characterized by a whitish discoloration beginning at the edges and corners, accompanied by cracking and spalling. This phenomenon occurs when sulfates react with the components of hardened concrete, forming compounds like calcium sulfate and calcium sulfoaluminate which occupy more space than the substances they replace, causing the concrete to expand and disrupt.
Sulfates from sources like soil, groundwater, or industrial effluents...

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Synthesis and Reaction Chemistry of Nanosize Monosodium Titanate
08:44

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Published on: February 23, 2016

Sodium trichloromethanesulfonate monohydrate.

Emiliana Damian1, Lars Eriksson, Magnus Sandström

  • 1Department of Physical, Inorganic and Structural Chemistry, Arrhenius Laboratory, Stockholm University, SE-10691 Stockholm, Sweden. emiliana@struc.su.se

Acta Crystallographica. Section C, Crystal Structure Communications
|September 7, 2006
PubMed
Summary

Sodium trichloromethanesulfonate monohydrate crystallizes with a unique structure. The study details the arrangement of its sodium ions, trichloromethanesulfonate anions, and water molecules, revealing specific hydrogen bonding and coordination patterns.

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Area of Science:

  • Crystal structure analysis
  • Inorganic chemistry
  • Solid-state chemistry

Background:

  • Sodium trichloromethanesulfonate monohydrate is an inorganic salt with potential applications.
  • Understanding its crystal structure is crucial for predicting its physical and chemical properties.

Purpose of the Study:

  • To determine the detailed crystal structure of sodium trichloromethanesulfonate monohydrate.
  • To elucidate the coordination environment of the sodium ion and the hydrogen bonding network.

Main Methods:

  • Single-crystal X-ray diffraction analysis
  • Crystallographic data collection and refinement
  • Analysis of molecular geometry and intermolecular interactions

Main Results:

  • The compound crystallizes in the P2(1)/a space group.
  • The trichloromethanesulfonate anion exhibits approximate C3v symmetry with staggered SO3 and CCl3 groups.
  • Water molecules form hydrogen bonds with sulfonate oxygen atoms and participate in bifurcated hydrogen bonding.
  • Sodium ions are coordinated by two water molecules and three sulfonate oxygen atoms in a square-pyramidal arrangement.

Conclusions:

  • The crystal structure provides a detailed understanding of the interactions within sodium trichloromethanesulfonate monohydrate.
  • The observed hydrogen bonding and coordination geometry influence the compound's stability and reactivity.
  • This structural information is fundamental for further research and potential applications.