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Ancillary ligand functionalization of cyanide-bridged S = 6 Fe(III)4Ni(II)4 complexes for molecule-based electronics

Dongfeng Li1, Sean Parkin, Rodolphe Clérac

  • 1Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055, USA.

Inorganic Chemistry
|September 12, 2006
PubMed

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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