Leaching of copper, chromium, and boron from treated timber during aboveground exposure

Field studies were conducted to evaluate leaching of Cu, Cr, and B from timber treated with a Cr, Cu, and B wood preservative and exposed aboveground in Spanish weathering conditions during one year with a total rainfall of approximately 500 mm. The effect of timber orientation (horizontal for decks and vertical for fences) on metal leaching was assessed. Leaching of metals after one year was higher for decks than for fences, with total amounts of metals leached being 226.6 and 87.8 mg/m2 for Cu, 199.5 and 42.4 mg/m2 for Cr, and 110.1 and 32.6 mg/m2 for B from decks and fences, respectively. Leaching rates did not drop constantly with time, because an increase in metal leaching, except for B, was observed at the end of the year after a long dry period. The order of metal emission varied with cumulative rainfall: Leaching of B was higher than Cr initially, but the opposite occurred at the end of the assay. Total emissions of Cu and Cr obtained in a laboratory assay were lower than those for decks and fences under field conditions when expressed per unit surface area (mg/m2), but they were similar to the values obtained for fences when expressed as a percentage of the initial amount. However, the percentage of B leached from wood was higher in laboratory than in field assays for both orientations, with the amount of B leached per unit surface area under laboratory conditions being higher than that leached from fences but lower than that leached from decks. Emission rates extrapolated to one year from laboratory data underestimated metal leaching from decks and overestimated emissions from fences.