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Removal of boron from aqueous solution by using neutralized red mud
Yunus Cengeloglu1, Ali Tor, Gulsin Arslan
1Selcuk University, Department of Chemistry, Campus, 42031 Konya, Turkey.
Neutralized red mud effectively removes boron from water. The Freundlich isotherm model accurately describes boron adsorption, which reaches equilibrium within 20 minutes across a wide pH range.
Area of Science:
- Environmental Science
- Water Treatment Technologies
- Adsorption Science
Background:
- Boron contamination in aqueous solutions poses environmental and health risks.
- Red mud, a byproduct of alumina production, is an abundant and low-cost material.
- Effective and economical methods for boron removal are crucial for water purification.
Purpose of the Study:
- To investigate the adsorptive removal efficiency of neutralized red mud for boron.
- To explore the influence of key parameters on boron adsorption.
- To evaluate the suitability of adsorption isotherm models for describing the process.
Main Methods:
- Batch equilibration technique was employed for adsorption studies.
- Experiments were conducted to assess the effects of pH, adsorbent dosage, initial boron concentration, and contact time.
- Adsorption data were fitted to Langmuir and Freundlich isotherm models.
Main Results:
- Boron removal showed minimal fluctuation within a pH range of 2-7.
- Adsorption equilibrium was achieved in approximately 20 minutes.
- The Freundlich isotherm model provided a better fit to the experimental sorption data compared to the Langmuir model.
Conclusions:
- Neutralized red mud is a promising adsorbent for boron removal from aqueous solutions.
- The adsorption process is relatively rapid and effective over a broad pH range.
- The Freundlich model effectively describes the boron adsorption mechanism onto neutralized red mud.
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