One-electron reduction of S-nitrosothiols in aqueous medium

V M Manoj1, H Mohan, U K Aravind

  • 1School of Chemical Sciences, Mahatma Gandhi University, Kottayam 686560, Kerala, India.

Summary

One-electron reduction of S-nitrosothiols (RSNO) by hydrated electrons releases nitric oxide (NO) and thiols. This reaction, crucial in biological systems, proceeds via a radical anion intermediate, not a thiyl radical.

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