Anomalous dynamic arrest in a mixture of large and small particles

We present molecular dynamics simulations of the slow dynamics of a mixture of large and small soft spheres with a large size disparity. The dynamics are investigated in a broad range of temperature and mixture composition. As a consequence of the large size disparity, large and small particles exhibit very different relaxation times. As previously reported for simple models of short-ranged attractive colloids and polymer blends, several anomalous dynamic features are observed: (i) sublinear behavior for mean-squared displacements, (ii) concave-to-convex crossover for density-density correlators, by varying the temperature or wave vector, and (iii) logarithmic decay for specific wave vectors of density-density correlators. These anomalous features are observed over time intervals extending up to four decades and strongly resemble predictions of the mode coupling theory (MCT) for state points close to higher-order MCT transitions, which originate from the competition between different mechanisms for dynamic arrest. For the large particles we suggest competition between soft-sphere repulsion and depletion effects induced by neighboring small particles. For the small particles we suggest competition between bulklike dynamics and confinement, respectively induced by neighboring small particles and by the slow matrix of large particles.