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Scanning pyroelectric microscopy revealing the spatial polarity distribution in topologically centric crystals of

N-R Behrnd1, G Couderc, M Wübbenhorst

  • 1Department of Chemistry and Biochemistry, University of Berne, Freiestrasse 3, CH-3012, Berne, Switzerland.

Physical Chemistry Chemical Physics : PCCP
|October 10, 2006
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The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...