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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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Induction of liquid crystallinity by self-assembled molecular boxes

Alessio Piermattei1, Marcel Giesbers, Antonius T M Marcelis

  • 1Laboratory of Supramolecular Chemistry & Technology, MESA+ Institute for Nanotechnology, University of Twente, 7500 AE Enschede, The Netherlands.

Angewandte Chemie (International Ed. in English)
|October 18, 2006
PubMed
Summary

No abstract available in PubMed .

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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
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Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...

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