Electrochemical behavior of cast Ti-Ag alloys
Masatoshi Takahashi1, Masafumi Kikuchi, Yukyo Takadai
1Division of Dental Biomaterials, Graduate School of Dentistry, Tohoku University, Sendai, Miyagi, Japan. m-tak@mail.tains.tohoku.ac.jp
Abstract:
Anodic polarization tests were performed in 0.9% NaCl and 1% lactic acid solutions to characterize the relationship between the corrosion behavior and the microstructures of cast Ti-Ag (5-40% Ag) alloys. The anodic polarization curves for the Ti-Ag alloys up to 17.5% Ag were similar to those for pure titanium in both solutions. On the other hand, an abrupt increase in the current density was observed for the alloys with more than 20% Ag in the NaCl solution and with more than 27.5% Ag in the lactic acid solution. The microstructures of the corroded alloy surfaces indicated the deterioration of precipitated intermetallic compounds along the grain boundaries. The Ti-Ag alloys up to 17.5% Ag had excellent corrosion resistance similar to that of pure titanium. The alloys with 20-25% Ag may be also used as dental alloys, since they passivated again immediately after preferential dissolution in the NaCl solution.
Related Concept Videos
Electrodeposition
Electrodeposition can...
Properties of Transition Metals
Electrogravimetric Analysis: Overview
To test the completeness of the...
Electrochemical Cells
Voltaic/Galvanic Cells
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Types of Reversible Electrodes

