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Nickel-catalysed intramolecular alkene insertion into cyclobutanones

Masahiro Murakami1, Shinji Ashida

  • 1Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto, 615-8510, Japan. murakami@sbchem.kyoto-u.ac.jp

Chemical Communications (Cambridge, England)
|November 4, 2006
PubMed
Summary

A nickel(0) catalyst facilitates a novel reaction, converting 3-styrylcyclobutanones into benzobicyclo[2.2.2]octenones. This transformation involves the intramolecular insertion of a vinyl group into the cyclobutanone ring structure.

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