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rac-(Z)-Ethyl 2-bromo-2-[(3R,5R)-3-bromo-5-methyltetrahydrofuran-2-ylidene]acetate
François Loiseau1, Reinhard Neier, Gaël Labat
1Institut de Chimie, Université de Neuchâtel, Rue Emile Argand 11, CH-2009 Neuchâtel, Switzerland. francois.loiseau@unine.ch
Abstract:
In the title compound, C9H12Br2O3, a (tetrahydrofuran-2-ylidene)acetate, the double bond has the Z form. In the tetrahydrofuran group, the relative configuration of the Br atom in the 3-position and the methyl group in the 5-position is anti. The compound crystallizes with two independent molecules per asymmetric unit and, in the crystal structure, the individual molecules are linked to their symmetry-equivalent molecules by C-H...O hydrogen bonds, so forming centrosymmetric hydrogen-bonded dimers.
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