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Updated: Jul 18, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
Published on: May 26, 2019
An ab initio investigation of zinc chloro complexes
Cory C Pye1, Christopher R Corbeil, Wolfram W Rudolph
1Department of Chemistry, Saint Mary's University, Halifax, Nova Scotia, Canada B3H 3C3. cory.pye@smu.ca
Abstract:
A series of geometry, frequency, and energy calculations of chloroaquazinc(II) complexes were carried out at up to the MP2/6-31+G* level. A thorough examination of all species up to and including hexacoordinate species, and with up to six chlorides, was carried out. The structures of the complexes are compared with experimental data where available. The solution chemistry of zinc(II) in the presence of chloride is discussed, and Raman spectra of zinc perchlorate with increasing amount of chloride are presented.
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