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An unexpected synthesis of ketene monothioacetals

Stéphanie Fabre1, Xavier Vila, Samir Z Zard

  • 1Laboratoire de Synthèse Organique associé au C. N. R. S., Département de Chimie, Ecole Polytechnique, F-91128 Palaiseau, France.

Chemical Communications (Cambridge, England)
|December 1, 2006
PubMed
Summary

Certain dithiocarbonates, also known as xanthates, can transform into ketene monothioacetals. This conversion is achieved by extruding sulfur using a base and an alkylating agent.

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