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Optimization of coagulation-flocculation process for pulp and paper mill effluent by response surface methodological

A L Ahmad1, S S Wong, T T Teng

  • 1School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Pulau Pinang, Malaysia. chlatif@eng.usm.my

Journal of Hazardous Materials
|December 13, 2006
PubMed
Summary

Optimizing pulp and paper wastewater treatment using coagulation-flocculation achieved 99% total suspended solids removal. The study identified optimal coagulant dosage and pH for efficient water recovery and sludge reduction.

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Area of Science:

  • Environmental Engineering
  • Water Treatment Technologies
  • Chemical Engineering

Background:

  • Coagulation-flocculation is an established method for treating wastewater laden with high concentrations of suspended solids.
  • Pulp and paper mill wastewater presents unique challenges due to its high suspended solids content.
  • Optimizing process variables is crucial for maximizing efficiency and achieving desired treatment outcomes.

Purpose of the Study:

  • To optimize the coagulation-flocculation process for pulp and paper mill wastewater.
  • To determine the ideal coagulant dosage and pH for enhanced total suspended solids (TSS) removal, reduced sludge volume index (SVI), and increased water recovery.
  • To develop predictive models for treatment efficiency based on operating parameters.

Main Methods:

  • Application of central composite face-centered design (CCFD) and response surface methodology (RSM).
  • Systematic variation of coagulant dosage and pH as key operating variables.
  • Statistical analysis including Analysis of Variance (ANOVA) to develop quadratic models and assess variable interactions.

Main Results:

  • Significant interactions between coagulant dosage and pH were observed for TSS removal and SVI.
  • No significant interaction was found between coagulant dosage and water recovery.
  • Developed quadratic models with a high coefficient of determination (R(2) > 0.99) for TSS removal, SVI, and water recovery.
  • Identified optimal conditions: 1045 mg/L coagulant dosage and pH 6.75.
  • Achieved 99% TSS removal, an SVI of 37 mL/g, and 82% water recovery under optimal conditions.

Conclusions:

  • The study successfully optimized the coagulation-flocculation process for pulp and paper wastewater.
  • The developed models accurately predict treatment performance, enabling efficient process control.
  • Optimal conditions provide a viable solution for high-efficiency wastewater treatment, resource recovery, and sludge management in the pulp and paper industry.