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Olive mill wastewater treatment: an experimental study
E Bettazzi1, M Morelli, S Caffaz
1Dipartimento di Ingegneria Civile, Università di Firenze, Via Santa Marta 3, 50139 Firenze, Italy.
Olive mill wastewaters (OMWs) pose environmental challenges due to high organic load. Advanced oxidation processes and fungal biodegradation effectively remove phenolic compounds from OMWs, offering viable treatment solutions.
Area of Science:
- Environmental Science
- Biotechnology
- Chemical Engineering
Background:
- Olive mill wastewater (OMW) is a major byproduct of Mediterranean agro-industry.
- OMWs present significant environmental hazards due to high organic load, acidity, and toxic phenolic/lipidic compounds.
- Current disposal methods, like soil application in Italy, are insufficient for managing OMW pollution.
Purpose of the Study:
- To investigate the efficiency and feasibility of advanced oxidation processes (AOPs) and biological treatments for OMW.
- To assess the removal of phenolic compounds from OMW using ozone, Fenton's reagents, and aerobic biodegradation.
- To evaluate the impact of oxidation pretreatment on the biological treatability of OMW.
Main Methods:
- Experimental trials conducted on real OMW from a large Italian mill and synthetic solutions.
- Application of ozone and Fenton's reagents for oxidation treatments.
- Aerobic biological treatment in a batch reactor using OMW without initial biomass inoculum.
Main Results:
- Ozone and Fenton's reagents achieved up to 95% removal of polyphenols from OMW and synthetic solutions.
- An indigenous fungal biomass developed in raw OMW, achieving 70% biodegradation of phenolic compounds.
- Oxidative pretreatment significantly enhanced the subsequent biological treatability of OMW.
Conclusions:
- AOPs are highly effective for rapid polyphenol removal from OMW.
- Fungal biodegradation offers a sustainable biological approach for OMW treatment, particularly for phenolic compounds.
- Combining oxidation pretreatment with biological treatment presents a promising strategy for efficient OMW management.
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