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Related Experiment Video

Updated: Jul 18, 2026

Conducting Miller-Urey Experiments
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Published on: January 21, 2014

Chemistry and cosmology.

John H Black1

  • 1Department of Radio and Space Science, Chalmers University of Technology, Onsala Space Observatory, SE-43992, Sweden.

Faraday Discussions
|December 29, 2006
PubMed
Summary

Early universe chemistry, involving hydrogen and helium, influenced cosmic structure. Calculations show H- absorption could distort the cosmic background radiation spectrum, offering a test for cosmological models.

Area of Science:

  • Cosmology
  • Astrochemistry

Background:

  • The early universe's evolution was governed by the chemistry of simple elements like hydrogen and helium.
  • Theoretical models of cosmic structure formation now integrate this primordial chemistry.
  • Cosmologists seek observational tests for competing universe models, including early departures from thermodynamic equilibrium.

Purpose of the Study:

  • To investigate the observable effects of primordial chemistry on the cosmic background radiation.
  • To calculate the evolution of chemical abundances in the early universe.
  • To determine if H- absorption can produce detectable spectral distortions.

Main Methods:

  • Detailed calculation of the abundance evolution for various hydrogen species (H, H+, H-, H2, H2+, H3+).
  • Modeling the spectral distortion of the cosmic background radiation caused by continuous absorption from H-.

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Main Results:

  • Continuous absorption by H- can create a spectral distortion in the cosmic background radiation.
  • The predicted distortion has a maximum at a frequency near nu/c = 9 cm-1 (1.1 mm wavelength).
  • The predicted distortion is within a factor of 5 of current observational limits.

Conclusions:

  • The detection of this spectral distortion would serve as a crucial test of our understanding of the universe's recombination epoch.
  • Primordial chemistry plays a significant role in observable cosmological phenomena.
  • Further observations could confirm or refute these predictions, refining cosmological models.