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Spontaneous vesicle formation of single chain and double chain cationic surfactant mixtures
Makoto Aratono1, Nami Onimaru, Yumi Yoshikai
1Department of Chemistry, Faculty of Sciences, Kyushu University, Fukuoka 812-8581, Japan. m.arascc@ mbox.nc.kyushu-u.ac.jp
Abstract:
The concentration vs composition diagram of aggregate formation of the dodecyltrimethylammonium bromide (DTAB) and didodecyldimethylammonium bromide (DDAB) mixture in aqueous solution at rather dilute region was constructed by analyzing the surface tension, turbidity, and electrical conductivity data and inspected by cryo-TEM images and dynamic light scattering data. Although the aqueous solution of DTAB forms only micelles, the transition from monomer to small aggregates and then to vesicle was found at 0.1 < X2
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