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Mg2Ru2Cl10O.16H2O.

Sihem Boufas¹, Hocine Merazig, Lamia Bendjeddou

¹Laboratoire de Chimie Moléculaire, du Contrôle de l'Environnement et des Mesures Physico-Chimiques, Faculté des Sciences, Département de Chimie, Université Mentouri de Constantine, 25000 Constantine, Algeria. boufas_sihem@yahoo.fr

Acta Crystallographica. Section C, Crystal Structure Communications

|January 9, 2007

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Dimagnesium mu-oxo-bis[pentachlororuthenate(IV)] hexadecahydrate, a novel crystalline compound, exhibits a unique layered structure. This structure is stabilized by hydrogen bonding interactions between its constituent ions and water molecules.

Area of Science:

Inorganic Chemistry
Crystallography
Materials Science

Background:

Ruthenium-oxygen-chlorine complexes represent an intriguing class of inorganic compounds.
Understanding the crystal structures of such complexes is crucial for predicting their properties and potential applications.

Purpose of the Study:

To elucidate the crystal structure of Mg2Ru2Cl10O.16H2O (dimagnesium mu-oxo-bis[pentachlororuthenate(IV)] hexadecahydrate).
To characterize the bonding and interactions within the crystal lattice.

Main Methods:

Single-crystal X-ray diffraction was employed to determine the crystal structure.
Analysis of atomic positions and site occupancies within the unit cell.

Main Results:

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The compound crystallizes in the monoclinic system with space group P2(1)/c.

The structure features layered arrangements of [Ru2Cl10O]4- anions and [Mg(H2O)6]2+ cations, interspersed with water molecules.

Hydrogen bonding (O-H...O and O-H...Cl) plays a key role in stabilizing the crystal structure.

Conclusions:

The detailed crystal structure of dimagnesium mu-oxo-bis[pentachlororuthenate(IV)] hexadecahydrate has been determined.
The layered architecture and hydrogen bonding network provide insights into the compound's stability.
This structural information is foundational for further investigations into the chemical and physical properties of this ruthenium complex.