2'-Hydroxycinnamaldehyde from stem bark of Cinnamomum cassia

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Synthesis of Esters Via a Greener Steglich Esterification in Acetonitrile
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Synthesis of Esters Via a Greener Steglich Esterification in Acetonitrile

Published on: October 30, 2018

B M Kwon, Y K Cho, S H Lee

    Planta Medica
    |April 1, 1996
    PubMed

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    Aldehydes and Ketones with HCN: Cyanohydrin Formation Overview01:32

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    Cyanohydrins are compounds that contain –CN and –OH groups on the same carbon atom. They are formed by the nucleophilic addition of the cyanide ions to the carbonyl group. Cyanide ions are highly basic and nucleophilic and can be generated from HCN under aqueous conditions. However, since HCN is a weak acid, the number of cyanide ions generated is very small. Hence, a small amount of base or KCN/NaCN is added to HCN to increase the concentration of the cyanide ions in the reaction mixture.