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Application methods affect phosphorus-induced lead immobilization from a contaminated soil.

Joon Ki Yoon1, Xinde Cao, Lena Q Ma

  • 1Soil and Water Science Department, University of Florida, Gainesville, FL 32611-0290, USA.

Journal of Environmental Quality
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Summary

Phosphate rock and phosphoric acid effectively immobilize lead (Pb) in contaminated soils. Mixing both with soil and layering phosphate rock proved most effective for reducing Pb leachability and mobility.

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Area of Science:

  • Environmental Science
  • Soil Science
  • Geochemistry

Background:

  • Lead (Pb) contamination in soils poses significant environmental and health risks.
  • Phosphate rock (PR) and phosphoric acid (PA) are recognized for their potential to immobilize heavy metals like Pb.
  • Optimizing PR and PA application methods is crucial for effective soil remediation.

Purpose of the Study:

  • To evaluate the effectiveness of different application methods of PR and PA for immobilizing Pb in contaminated soil.
  • To compare the impact of mixing versus layering PR and applying PA in single or multiple doses.
  • To assess the reduction in leachable Pb using TCLP-Pb and PBET-Pb.

Main Methods:

  • A column experiment was conducted using contaminated soil treated with PR and PA at a P/Pb molar ratio of 4.
  • PR was applied either mixed with soil or as a layer; PA was applied as an aqueous solution.
  • Incubation for 4 weeks followed by analysis of total and soluble Pb and P, TCLP-Pb, and PBET-Pb.

Main Results:

  • Phosphate application significantly reduced leachable Pb below the EPA standard in all treatments.
  • Mixing both PR and PA with soil maximally reduced TCLP-Pb (up to 95%) and PBET-Pb (25-42%).
  • Layering PR effectively reduced Pb migration (73-79%) and mitigated soil acidification and P eutrophication.

Conclusions:

  • Phosphate application is a viable strategy for immobilizing Pb in contaminated soils.
  • Combining soil mixing of PR and PA with PR layering offers a robust remediation approach.
  • This method effectively reduces Pb leachability, bioavailability, and mobility while minimizing adverse environmental impacts.