Reaction between diiodide anion radicals in ionic liquids

Kenji Takahashi1, Shingo Sakai, Hiroaki Tezuka

  • 1Division of Material Science, Graduate School of Natural Science and Technology, Kanazawa University, Kanazawa 920-1192, Japan. ktkenji@t.kanazawa-u.ac.jp

Summary

Electron photodetachment from iodide ions forms diiodide anion radicals. In ionic liquids, their reaction rates approach diffusion limits due to weakened electrostatic repulsion from Coulombic shielding.

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