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Detection of chemical warfare simulants by phosphorylation of a coumarin oximate
Karl J Wallace1, Ruth I Fagbemi, Frantz J Folmer-Andersen
1Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, TX, USA.
Abstract:
The detection of chemical warfare simulants is attained by the PET mechanism that gives an "off-on" fluorescent response with a half-life of approximately 50 ms upon phosphorylation of a reactive oximate functionality; the X-ray crystal structure of the oximate was also obtained and is discussed.
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