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13C6-Glucose Labeling Associated with LC-MS: Identification of Plant Primary Organs in Secondary Metabolite Synthesis
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A New Stereoidal Saponin from Polygonatum officinale

Z Janeczko1, P E Jansson, J Sendra

  • 1Department of Pharmacognosy, Academy of Medicine, Kraków, Poland.

Planta Medica
|February 1, 1987
PubMed

Abstract:

Methanol extract of defatted rhizomes of POLYGONATUM OFFICINALE All. yielded a mixture of steroidal saponins. The structures of polyfuroside and odospiroside have been elucidated.

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Esters to Carboxylic Acids: Saponification01:25

Esters to Carboxylic Acids: Saponification

Esters can be hydrolyzed to carboxylic acids under acidic or basic conditions. Base-promoted hydrolysis of esters is a nucleophilic acyl substitution reaction in which esters react with an aqueous base, followed by an acid to give carboxylic acids. This reaction is also known as saponification because it forms the basis for making soaps from fats.
The reaction requires a base in stoichiometric amounts, which participates in the reaction and is not regenerated later. So, the base acts as a...

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