An Egsnrc investigation of the P(TP) correction factor for ion chambers in kilovoltage X rays

As part of the standard practice for obtaining consistent ion chamber measurements with cavities open to the surrounding atmosphere, the raw measured response is corrected to the response at a reference temperature and pressure using the standard temperature-pressure correction factor (P(TP)). In this study, the EGSnrc Monte Carlo code was used to investigate the validity of the P(TP) correction factor for kilovoltage x rays incident on various geometrically distinct ion chambers. The calculated P(TP)-corrected chamber response deviated by over 2% relative to expected values for a 40 kV spectrum incident on a graphite thimble chamber at an air density typical of Mexico City. The relative deviation from the expected response was much worse for a large spherical graphite chamber, exceeding 16% at an air density of 0.6 kg/m3 (approximately 0.5 atm at 22 degrees C) for the same beam energy. The breakdown of the P(TP) correction factor was also observed for a 26 kV mammography spectrum incident on two mammography chambers. For 60Co beams, the P(TP) correction factor behaved as expected. For day-to-day variations in pressure, only a negligible of the P(TP) correction factor was observed with low x-ray energies. Factors contributing to the breakdown of the P(TP) correction factor at low x-ray energies and large pressure variations, such as the range of electrons, the material of the wall, the chamber dimensions and air-photon interactions, are discussed in depth.