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Related Concept Videos

Supercritical Fluid Chromatography01:18

Supercritical Fluid Chromatography

Supercritical fluid chromatography (SFC) provides a beneficial substitute for gas chromatography (GC) and liquid chromatography (LC) for certain samples because it merges the top attributes of both techniques. SFC allows the separation and analysis of compounds that GC or LC does not easily manage. These compounds are traditionally nonvolatile or thermally unstable, making GC unsuitable and lacking functional groups required for HPLC analysis.
SFC utilizes a supercritical fluid mobile phase,...
Phase Diagrams02:39

Phase Diagrams

A phase diagram combines plots of pressure versus temperature for the liquid-gas, solid-liquid, and solid-gas phase-transition equilibria of a substance. These diagrams indicate the physical states that exist under specific conditions of pressure and temperature and also provide the pressure dependence of the phase-transition temperatures (melting points, sublimation points, boiling points). Regions or areas labeled solid, liquid, and gas represent single phases, while lines or curves represent...
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When a force is applied parallel to the top surface of a solid, it resists the applied force due to the internal frictional forces between the layers of the solid known as shearing resistance. However, when the force is removed, the shearing forces restore the original shape of the solid. Other deformation forces also cause temporary changes in shape if the forces are not beyond a threshold magnitude. Solids tend to retain their shape, making the study of their rest and motion easier. Beyond...
Characteristics of Fluids01:31

Characteristics of Fluids

Fluids differ from solids primarily in their molecular structure and stress response. Solids have tightly packed molecules with strong intermolecular forces, maintaining their shape and resisting deformation. In contrast, fluids have molecules spaced farther apart with weaker forces, allowing them to flow and deform easily.
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Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement (no fixed shape); in a gas, they are far apart with no regular arrangement (no fixed shape). Particles in a solid vibrate about fixed positions (cannot flow) and do not generally move in relation to one another; in a liquid, they move past each other (can flow) but remain in essentially constant contact; in a gas, they move...
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Supercritical Nitrogen Processing for the Purification of Reactive Porous Materials
09:05

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Published on: May 15, 2015

Liquidlike behavior of supercritical fluids.

F Gorelli1, M Santoro, T Scopigno

  • 1Research Center SOFT-INFM-CNR, Università di Roma La Sapienza, I-00185, Roma, Italy.

Physical Review Letters
|February 7, 2007
PubMed
Summary

Supercritical fluid oxygen exhibits liquid-like dynamics, with sound velocity exceeding hydrodynamic predictions. This behavior is linked to the liquid-vapor coexistence line and the non-metal to metal transition in dense fluids.

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Area of Science:

  • Condensed matter physics
  • Physical chemistry
  • Fluid dynamics

Background:

  • Understanding fluid dynamics under extreme conditions is crucial for various scientific fields.
  • Supercritical fluids exhibit unique properties that bridge the gap between liquid and gas phases.

Purpose of the Study:

  • To investigate the high-frequency dynamics of fluid oxygen under high pressure and room temperature.
  • To identify the boundary between liquid-like and gas-like dynamics in supercritical fluids.

Main Methods:

  • Inelastic X-ray scattering (IXS) was employed to probe the dynamics of fluid oxygen.
  • Experimental data were compared with existing literature data for various fluids.

Main Results:

  • Fluid oxygen under supercritical conditions (T ≈ 2Tc, P > 100Pc) showed a sound velocity approximately 20% higher than the hydrodynamic value, indicating liquid-like dynamics.
  • The extrapolation of the liquid-vapor coexistence line in the reduced pressure-temperature phase diagram was identified as the critical boundary.
  • This boundary closely aligns with the non-metal to metal transition observed in shock-compressed dense fluids.

Conclusions:

  • A connection exists between structural changes and transport properties in dense fluids.
  • The liquid-vapor coexistence line extrapolation serves as a key indicator for transitions in fluid dynamics.
  • Supercritical fluid dynamics can exhibit characteristics typically associated with liquids, even at high temperatures and pressures.