Geometry of phenylene motion in polycarbonate from NMR spectroscopy and neutron scattering

In view of the importance of molecular dynamics in condensed matter both time scale and geometry of such processes should be determined experimentally. Whereas many techniques are available for the former, only NMR spectroscopy and neutron scattering can provide detailed information on the latter. Because of the different time scales of the dynamics, which the two techniques can detect best, direct comparisons of probing the geometry of the dynamics in the same system are scarce. Here we present such a comparison for the complex rotational motion of the phenylene groups in amorphous polycarbonate based on published (2)H NMR and newly recorded (13)C NMR data covering a wide temperature range, and recent quasielastic neutron scattering (QENS) data. We show that the results of the two techniques are in remarkable agreement, provided the data are consistently analyzed. No evidence is found for additional motions characterized by 90 degrees flips recently deduced from QENS data alone. Instead, the phenylene motion in the glassy state displays a broad heterogeneous distribution of rotational angles, about 80 degrees in width, centered at a flip angle of 180 degrees , which stays essentially constant over a wide temperature range. Thus, the phenylene motion that can consistently be observed in NMR and neutron scattering experiments is sensitive to the local packing.