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Updated: Jul 17, 2026

Isolation and Compositional Analysis of Plant Cuticle Lipid Polyester Monomers
Published on: November 22, 2015
Suberin: a biopolyester of plants' skin
1Instituto Superior de Agronomia, Universidade Técnica de Lisboa, 1349-017 Lisboa, Portugal. jograca@isa.utl.pt
Abstract:
Suberin is a biopolymer that acts as a barrier between plants and the environment. It is known to be a complex polyester based on glycerol and long-chain alpha,omega-diacids and omega-hydroxyacids. How these monomeric units are assembled at a macromolecular level remains mostly unknown. The knowledge gathered in the last 10 years has opened new insights into suberin structure. Suberin oligomeric blocks have been obtained after the partial depolymerization of the biopolymer, and in-situ studies by solid-state (13)C NMR spectroscopy have shown different molecular domains and how they are spatially related. Based on these latter developments, a model is proposed for the suberin macromolecular structure. The uniqueness of the suberin polyester opens perspectives for its use as a source of bio-based materials.
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