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Integrating a Triplet-triplet Annihilation Up-conversion System to Enhance Dye-sensitized Solar Cell Response to Sub-bandgap Light
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A novel blue dye for near-IR 'dye-sensitised' solar cell applications

Anthony Burke1, Lukas Schmidt-Mende, Seigo Ito

  • 1Laboratoire de Photonique et Interfaces, Institute des Sciences et Ingénierie Chimiques, Ecole Polytechnique Federal Lausanne, CH-1015, Lausanne, Switzerland.

Chemical Communications (Cambridge, England)
|February 15, 2007
PubMed

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Aryldiazonium Salts to Azo Dyes: Diazo Coupling01:11

Aryldiazonium Salts to Azo Dyes: Diazo Coupling

The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.