Related Experiment Video
Updated: Jul 16, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
A second polymorph of bis(dimethylphosphino)dimethylphosphonium trifluoromethanesulfonate
Jan J Weigand1, Reagan J Davidson, T Stanley Cameron
1Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada B3H 4J3.
Abstract:
The title compound, C(6)H(18)P(3)(+) x CF(3)SO(3)(-), crystallizes in two polymorphic forms in the space groups P2(1)/c and Pnma. In the orthorhombic form, the two crystallographically independent molecular units lie across a crystallographic mirror plane. The compound lacks traditional hydrogen-bond donors and, hence, is held together by weak C-H...O and C-H...F interactions, forming layers. The second polymorph was obtained as a by-product from the reaction of 1,3-bis(2,6-dimethylphenyl)-2,4-ditriflato-1,3,2,4-diazadiphosphetidine with tetramethyldiphosphine.
Related Concept Videos
Preparation and Reactions of Sulfides
Hybridization of Atomic Orbitals II
Molecular Shape and Polarity
Hybridization of Atomic Orbitals I
Predicting Molecular Geometry
Molecular Geometry and Dipole Moments

