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Preparation of N-(2-alkoxyvinyl)sulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
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Preparation of N-(2-alkoxyvinyl)sulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines

Published on: January 3, 2018

Phosphazene base-promoted functionalization of aryltrimethylsilanes

Koichi Suzawa1, Masahiro Ueno, Andrew E H Wheatley

  • 1Graduate School of Pharmaceutical Sciences, Tohoku University, Aramaki Aza Aoba 6-3, Aoba-ku, Sendai 980-8578, Japan.

Chemical Communications (Cambridge, England)
|March 10, 2007
PubMed
Summary

Researchers activated aryl-silicon bonds in aryltrimethylsilanes using a t-Bu-P4 base catalyst. This method enabled selective functionalization of aromatic rings, even without strong electron-withdrawing groups.

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