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Related Experiment Videos

195Pt NMR--theory and application.

Brett M Still1, P G Anil Kumar, Janice R Aldrich-Wright

  • 1Nanoscale Organisation and Dynamics Group, College of Health and Science, University of Western Sydney, Penrith South DC, NSW 1797, Australia.

Chemical Society Reviews
|March 28, 2007
PubMed
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Progress in nuclear magnetic resonance spectroscopy·2026

Platinum-195 Nuclear Magnetic Resonance (195Pt NMR) has advanced significantly, offering valuable insights into catalysis, intermetallics, and drug interactions. Recent developments enhance its utility across diverse scientific fields.

Area of Science:

  • Inorganic Chemistry
  • Materials Science
  • Chemical Physics

Background:

  • Platinum-195 Nuclear Magnetic Resonance (195Pt NMR) spectroscopy is a powerful tool for characterizing platinum-containing compounds.
  • Over the past 25 years, significant advancements have been made in both the theoretical understanding and experimental application of 195Pt NMR.

Purpose of the Study:

  • To provide a critical review of the progress in 195Pt NMR over the last 25 years.
  • To discuss recent applications of 195Pt NMR in catalysis, mechanistic studies, intermetallics, and drug binding.
  • To present a compilation of experimental and theoretical data on 195Pt NMR chemical shifts, coupling constants, and relaxation.

Main Methods:

  • Literature review of studies published over the last 25 years.

Related Experiment Videos

  • Compilation and analysis of experimental and theoretical 195Pt NMR data.
  • Discussion of applications in catalysis, mechanistic studies, intermetallics, and drug binding.

    • Main Results:

    • Comprehensive data on 195Pt NMR chemical shifts for Pt(0), Pt(II), Pt(III), and Pt(IV) complexes are presented.
    • Extensive collection of 195Pt coupling constants with various nuclei.
    • Data on 195Pt relaxation times are included.
    • Recent applications demonstrate the utility of 195Pt NMR in diverse research areas.

    Conclusions:

    • 195Pt NMR has evolved into a rich source of information due to theoretical and experimental advancements.
    • The technique is crucial for understanding platinum chemistry, catalysis, materials, and biological interactions.
    • This review consolidates key data and highlights the expanding scope of 195Pt NMR applications.