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Updated: Jul 15, 2026

Patterning of Microorganisms and Microparticles through Sequential Capillarity-assisted Assembly
Published on: November 4, 2021
Spontaneous formation of micrometer-size inorganic peapods
Soumyajit Roy1, Maria T Rijneveld-Ockers, Jan Groenewold
1Van't Hoff Laboratory for Physical and Colloid Chemistry, Debye Institute, University of Utrecht, Padualaan 8, 3584 CH Utrecht, The Netherlands. s.roy@chem.uu.nl
Abstract:
We show that polyoxometalate (ammonium phosphomolybdate) Keggin in aqueous dispersions upon sonication spontaneously transforms into micrometer-sized, peapod-shaped structures. The formation of these peapods is preceded by the generation of spherical aggregates. The particles have been characterized experimentally by time-resolved dynamic light scattering (DLS), transmission electron microscopy (TEM), and scanning TEM with a high-angle annular dark field detector (STEM-HAADF) for energy-dispersive X-ray (STEM/EDX) elemental analyses. A pathway for the phenomenon is proposed.
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