Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

LiMn3(SeO3)2(HSeO3)6.

Magnus G Johnston1, William T A Harrison

  • 1Department of Chemistry, University of Aberdeen, Aberdeen AB24 3UE, Scotland.

Acta Crystallographica. Section C, Crystal Structure Communications
|April 7, 2007
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Piperazin-1-ium tri-aqua-di-bromido-sodium.

IUCrData·2026
Same author

Different packing motifs mediated by hydrogen bonds in the hydro-chloride salts of two pyridoxal <i>N</i>-acyl-hydrazone derivatives.

Acta crystallographica. Section E, Crystallographic communications·2025
Same author

Stereoview Images of Hydrogen-Bonded Quinoxalines with a Helical Axis; Pyrimidines and a Pyridazine That Form Extended Tapes.

International journal of molecular sciences·2024
Same author

Sequential Nucleophilic Aromatic Substitution Reactions of Activated Halogens.

International journal of molecular sciences·2024
Same author

Poly[3-methyl-pyridinium [(μ<sub>2</sub>-di-hydrogen phosphito)bis(μ<sub>3</sub>-hydrogen phosphito)dizinc]].

IUCrData·2024
Same author

Chiral Thianthrenes.

International journal of molecular sciences·2024

This study details the crystal structure of lithium trimanganese bis[trioxoselenate(IV)] hexakis[hydrogentrioxoselenate(IV)], revealing a dense 3D network of metal-oxygen polyhedra and hydrogen bonding critical for its packing.

Area of Science:

  • Inorganic Chemistry
  • Crystal Engineering
  • Materials Science

Background:

  • Understanding the structural intricacies of complex inorganic compounds is crucial for materials development.
  • Lithium and manganese selenates represent a class of compounds with potential applications in various fields.
  • Detailed structural analysis provides fundamental insights into chemical bonding and network formation.

Purpose of the Study:

  • To elucidate the detailed crystal structure of lithium trimanganese bis[trioxoselenate(IV)] hexakis[hydrogentrioxoselenate(IV)].
  • To characterize the coordination environments of manganese, lithium, and selenium atoms within the crystal lattice.
  • To identify the role of hydrogen bonding in the overall crystal packing and stability.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the atomic arrangement.

Related Experiment Videos

  • Analysis of coordination polyhedra (octahedra and pyramids) to describe the structural framework.
  • Identification and analysis of intermolecular interactions, including hydrogen bonds.

    • Main Results:

    • The compound features a dense three-dimensional structure built from vertex-sharing Mn(III)O(6) octahedra, SeO(3) and HSeO(3) pyramids, and Li(OH)(6) octahedra.
    • Specific site symmetries were determined for Mn, Li, and one Se atom (-1, -3, and 3, respectively).
    • An O-H...O hydrogen bond was identified as a key factor in the crystal packing.

    Conclusions:

    • The complex structure arises from the specific arrangement and connectivity of inorganic polyhedra.
    • The identified hydrogen bond plays a significant role in stabilizing the three-dimensional framework.
    • This structural characterization provides a foundation for exploring the properties and potential applications of this lithium-manganese-selenium compound.